STADIUM 1 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. [1] Daniil Medvedev vs [Q] Tomas Machac
2. [4] Rafael Nadal vs Sebastian Korda
3. [5] Paula Badosa vs Tereza Martincova (non prima ore: 00:00)
4. [WC] Jack Sock vs [5] Stefanos Tsitsipas (non prima ore: 03:00)
5. Naomi Osaka vs [21] Veronika Kudermetova (non prima ore: 05:00)
STADIUM 2 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. Jasmine Paolini vs [2] Aryna Sabalenka
2. [6] Maria Sakkari vs Katerina Siniakova
3. Alejandro Davidovich Fokina vs [13] Denis Shapovalov
4. [18] Leylah Fernandez vs Amanda Anisimova (non prima ore: 03:00)
5. [32] Federico Delbonis vs [WC] Nick Kyrgios
STADIUM 3 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. [19] Carlos Alcaraz vs Mackenzie McDonald
2. [17] Reilly Opelka vs Lorenzo Musetti
3. [Q] Christopher Eubanks vs [8] Casper Ruud
4. [13] Victoria Azarenka vs [LL] Astra Sharma (non prima ore: 02:00)
5. [14] Jessica Pegula vs [Q] Marie Bouzkova
STADIUM 4 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. Aliaksandra Sasnovich vs [27] Petra Kvitova
2. Kristina Kucova vs [4] Anett Kontaveit
3. Shelby Rogers vs [10] Jelena Ostapenko
4. [10] Jannik Sinner vs Laslo Djere (non prima ore: 02:00)
5. [25] Karen Khachanov vs Jenson Brooksby
STADIUM 5 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. Federico Coria vs [27] Daniel Evans
2. Hubert Hurkacz / Lukasz Kubot vs [6] Tim Puetz / Michael Venus
3. [12] Cameron Norrie vs Pedro Martinez
4. Benjamin Bonzi vs [21] Lorenzo Sonego
STADIUM 6 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. [Q] J.J. Wolf vs [15] Roberto Bautista Agut
2. Filip Krajinovic vs [26] Gael Monfils
3. Fabio Fognini vs [18] Nikoloz Basilashvili
4. Carlos Alcaraz / Pablo Carreno Busta vs Taylor Fritz / Tommy Paul
STADIUM 7 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. Nicolas Mahut / Fabrice Martin vs [3] Marcel Granollers / Horacio Zeballos
2. Marcelo Arevalo / Jean-Julien Rojer vs [5] John Peers / Filip Polasek
3. Andres Molteni / Diego Schwartzman vs Tomislav Brkic / Nikola Cacic
STADIUM 8 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. [30] Marketa Vondrousova vs [LL] Magdalena Frech
2. [31] Viktorija Golubic vs Yulia Putintseva
3. [Q] Kaja Juvan vs [32] Sara Sorribes Tormo
4. Yifan Xu / Zhaoxuan Yang vs Hao-Ching Chan / Magda Linette
STADIUM 9 – Ora italiana: 20:00 (ora locale: 11:00 am)
1. [20] Elise Mertens vs Marta Kostyuk
2. Alison Van Uytvanck vs [17] Elena Rybakina
3. [Q] Daria Saville vs [9] Ons Jabeur
4. [DA SR] Kirsten Flipkens / Sania Mirza vs [5] Gabriela Dabrowski / Giuliana Olmos